Ammonia (NH3): Physicochemical properties
Release time:
2018-11-05
Ammonia (NH3): Physicochemical properties
1. At normal temperature and pressure, ammonia is a colorless, toxic gas with a characteristic pungent odor and is lighter than air. Ammonia is stable at room temperature, but it decomposes into hydrogen and nitrogen at high temperatures. It decomposes at 450-500℃ under one atmospheric pressure. If iron, nickel or other catalysts are present, it can decompose at 300℃. 2NH3---------3H2+N2.
2. The molecular weight of ammonia is 17.031. Its boiling point is -33.35℃ under standard conditions, critical temperature is 132.4℃, critical pressure is 1127 Kpa, critical specific volume is 4.130 L/kg, and freezing point under standard conditions is -77.7℃.
3. Ammonia is combustible in air, but it is generally difficult to ignite. If it is continuously exposed to a fire source, it will burn, and sometimes it can also cause explosions. If there are oils or other combustible substances, it is easier to ignite. When burning in oxygen, it produces a yellow flame and generates nitrogen and water. 4NH3+3O2----------2N2+6H2O.
4. Ammonia can also explode in nitrous oxide, with an explosion concentration limit of 2.2%-72%.
5. Ammonia is slightly soluble in methanol, ethanol, dichloromethane and ether.
6. The latent heat of vaporization of liquid ammonia is very large, second only to water, being 301.8 Cal/g at 0℃. Therefore, it has properties similar to water and can dissolve many substances. Its solution also exhibits many properties similar to aqueous solutions. Liquid ammonia can dissolve ammonium salts, various metal salts, hydrochloric acid, iodides, phenols and amines.
7. Ammonia is toxic. The maximum allowable concentration is 25 ppm (18 mg/m³). Ammonia is mainly absorbed through the respiratory tract, but it can also be absorbed through the skin. Ammonia is dangerous when mixed with certain substances.
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